Quantitative Elemental Analysis of Organic Compounds.

IMPORTANT

Quantitative Elemental Analysis of Organic Compounds.: Overview

This topic covers concepts, such as, Quantitative Analysis of Organic Compounds, Estimation of Carbon and Hydrogen, Reactions for Estimation of Oxygen & Expression for Estimation of Oxygen etc.

Important Questions on Quantitative Elemental Analysis of Organic Compounds.

MEDIUM
IMPORTANT

In Carius method of estimation of halogens, 250 mg of an organic compound gave 141 mg of AgBr. The percentage of bromine in the compound is : (atomic mass Ag = 108; Br = 80)

EASY
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Carius method is used to estimate which of the following compounds?

MEDIUM
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Carius method is used for the estimation of halogen. 0.24 g of an organic compound gave 0.36 g of silver bromide. Percentage of bromine present in the compound is
 

MEDIUM
IMPORTANT

In quantitative analysis of carbon and hydrogen in an organic compound, let the mass of organic compound be m g, mass of water and carbon dioxide produced be m1 and m2 g respectively. The percentage of carbon is given as:

 

EASY
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In which of the following methods the organic compound yields nitrogen gas by heating it with copper(II) oxide in the presence of carbon dioxide gas.

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Draw the experimental set up of the estimation of nitrogen by Kjeldahl's method.

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Mention the reaction which involved in the estimation of carbon and hydrogen.

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Mention the reaction of carius method for the determination of sulphur. 

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Using Duma's method for estimating nitrogen, 1 g of an organic compound X' gave 82 ml of nitrogen, collected at 27°C and 750 mm Hg pressure. If the aqueous tension at 27°C is 30 mm Hg pressure, then the percentage of nitrogen in the given compound X is

HARD
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Which of the following method is used for the estimation of oxygen in an organic compound?

HARD
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The ammonia evolved from the treatment of 0.30 g of an organic compound for the estimation of nitrogen was passed in 100 mL of 0.1 M Sulphuric acid. The excess of acid required 20 mL of 0.5 M Sodium hydroxide solution for complete neutralization. The percentage of nitrogen in the organic compound is (Report the answer in the nearest integer).

MEDIUM
IMPORTANT

0.25 gm of organic compound on analysis by Dumas method produce 32 ml of nitrogen gas at STP. The percentage of nitrogen is?

EASY
IMPORTANT

Which one of the following methods can be used to find out the percentage composition of halogen present in an organic compound?

MEDIUM
IMPORTANT

0.35 g of an organic compound in Duma's estimation for nitrogen gave 55 ml of nitrogen at 300 K and 715 mm pressure. If the aqueous tension at 300 K is 15 mm of Hg pressure, the percentage of nitrogen in the compound is: